Write a mechanism for the conversion of the aldol addition product, 3-hydroxy-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propanone, to the aldol condensation product, (E)-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propenone. Be as complete as possible and show electron flow for all steps.

Answers

Answer 1

Solution :

"Aldol" stands for the abbreviation, aldehyde and alcohol. When a ketone or an aldehyde's enolate reacts with the carbonyl of a  molecule at the alpha carbon, under the acidic or basic conditions so as to obtained the ketone or β-hydroxy aldehyde, is known as an aldol reaction.

For the conversion of the aldol addition product of a 3-hydroxy-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propanone to an aldol condensation product of (E)-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propenone, the mechanism is given in the diagram a below :

Write A Mechanism For The Conversion Of The Aldol Addition Product, 3-hydroxy-3-(4-nitrophenyl)-1-(2-pyridyl)-1-propanone,

Related Questions

A 90-m3 basement in a residence is found to be contaminated with radon coming from the ground through the floor drains. The concentration of radon in the room is 1.5 Bq/L under steady-state conditions. The room behaves as a CSTR and the decay of radon is a first-order reaction with a decay rate constant of 2.09 3 1026 s21 . If the source of radon is closed off and the room is vented with radon-free air at a rate of 0.14 m3 /s, how long will it take to lower the radon concentration to an acceptable level of 0.15 Bq/L

Answers

Answer:

25 minutes

Explanation:

V = Volume = [tex]90\ \text{m}^3[/tex]

[tex]C_0[/tex] = Radon concentration under steady state = 1.5 Bq/L

k = Radon decay rate = [tex]2.09\times 10^{-6}\ \text{s}^{-1}[/tex]

[tex]Q[/tex] = Venting rate = [tex]0.14\ \text{m}^3/\text{s}[/tex]

[tex]C_f[/tex] = Final concentration of radon = 0.15 Bq/L

Theoretical detention time is given by

[tex]\theta=\dfrac{V}{Q}\\\Rightarrow \theta=\dfrac{90}{0.14}\\\Rightarrow \theta=642.86\ \text{s}[/tex]

We have the relation

[tex]C_f=C_0e^{-(\dfrac{1}{\theta}+k)t}\\\Rightarrow t=\dfrac{\ln\dfrac{C_f}{C_0}}{-(\dfrac{1}{\theta}+k)}\\\Rightarrow t=\dfrac{\ln\dfrac{0.15}{1.5}}{-(\dfrac{1}{642.86}+2.09\times 10^{-6})}\\\Rightarrow t=1478.25\ \text{s}=\dfrac{1478.25}{60}=24.63\approx 25\text{minutes}[/tex]

The time taken to reach the acceptable level of concentration is 25 minutes.

2 Nal + Pb(NO3)2
2 NaNO3
+
Pb12
What are the reactants in this equation?

Answers

I think it may be A but I’m not to certain

Answer:

[tex]\boxed {\boxed {\sf A. \ NaI \ and \ Pb(NO_3)_2}}[/tex]

Explanation:

In a chemical reaction, the reactants are the substances that start the reaction and change into other substances. The results at the end of the reaction are products.

Typically, the reactants are to the left of the arrow, while products are to the right.

reactants ⇒ products

We are given this chemical equation:

[tex]2 \ NaI + Pb(NO_3)_2 \rightarrow 2NaNO_3 +PbI_2[/tex]

We are asked to find the reactants. Remember, these go into the reaction and are on the left.

[tex]\bold {2 \ NaI + Pb(NO_3)_2 } \rightarrow 2NaNO_3 +PbI_2[/tex]

Therefore, the reactants are NaI (sodium iodide) and Pb(NO₃)₂ (lead nitrate). Choice A is correct.

The overall redox equation for the voltaic cell can be written as ^^^. What is being reduced in this forward reaction?

Answers

Answer:

Cu⁺² is being reduced in that reaction.

Explanation:

Zn(s) + Cu⁺²(aq) → Zn⁺²(aq) + Cu(s)

When a substance is reduced, its oxidation number is reduced -changing to a lower value than original-.

Cu⁺² turned into Cu. Meaning that the oxidation number changed from +2 to 0.

Thus, Cu⁺² is being reduced in that reaction.

Predict the product for the following reaction sequence.3,4-dimethyl-7-nonanol 3,4-dimethyl-7-nonanone 6,7-dimethyl-3-nonanone 6,7-dimethyl-3-nonanal 6,7-dimethyl-3-nonanol

Answers

Answer:

Hello your question is incomplete attached below is the complete question

answer : 6,7-dimethyl-3-nonanone ( B )

Explanation:

The product for the following reaction sequence as attached below is

6,7-dimethyl-3-nonanone

The following reaction sequence can be categorized under Carbon Nucleophiles.

Carbon Nucleophiles which can be used to convert  aldehydes and ketones into  carboxylic acids or alkenes.

The product for the given reaction sequence is 6,7-dimethyl-3-nonanone.

IUPAC (International Union of Pure and Applied Chemistry) naming is a systematic method used to name chemical compounds according to a set of rules established by the IUPAC.

The purpose of IUPAC naming is to provide a consistent and unambiguous way to communicate the structure of a compound through its name.

The outcome of the subsequent chain of reactions, which is appended below, is 6,7-dimethyl-3-nonanone

Under the heading of Carbon Nucleophiles, the following reaction chain can be categorised.

Aldehydes and ketones can be transformed into carboxylic acids or alkenes using carbon nucleophiles.

Thus, the answer is 6,7-dimethyl-3-nonanone.

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Your question seems incomplete, the probable complete question is:

What is the value of the equilibrium constant K ?

Answers

Answer:

K = 0.0209

Explanation:

K = [tex]\frac{[H_{2}][I_{2}]}{[2HI]^{2}}[/tex]

K = [tex]\frac{[4.35 x 10^{-2} ][2.79 x 10^{-2} ]}{[0.241]^{2} }[/tex]

K = 0.0208958

K = 0.0209

The particle in the atom with a negative charge is the...

Answers

Answer: electrons

Explanation: An atom consists of a positively charged nucleus, surrounded by one or more negatively charged particles called electrons.

The reason for using 1-propanol as the solvent of choice for recrystallization is that triphenylphosphine oxide is more soluble in 1-propanol than the alkene product because triphenylphosphine oxide can use its oxygen to hydrogen-bond to 1-propanol, whereas the alkene has no hydrogen-bonding capability. Triphenylphosphine oxide, therefore, is removed based on its polarity and H-bonding ability.

a. True
b. False

Answers

Answer:

True

Explanation:

Hydrogen bonding is a bond that exists between hydrogen and a highly electronegative element such as oxygen, nitrogen, fluorine etc.

The greater solubility of the triphenylphosphine oxide owes to the hydrogen bonded interaction between it and the 1-propanol.

The alkene lacks such hydrogen bonded interaction because it does not have a highly electronegative atom in its structure.

Hence, triphenylphosphine oxide is removed based on its polarity and hydrogen bonding ability.

Which of these benefits the grassland by allowing light, warmth, moisture, and nutrients back into the soil?
fires
ponds
trees
rainfall

Answers

Answer:

Trees

Explanation:

I think sorry if I get it wrong

NEED HELP FOR THIS ONE

Answers

Answer:

C₆H₁₂O₆ + 6 O₂ = 6 CO₂ + 6 H₂O

2 KO₂ + H₂O = 2 KOH + 1.5 O₂

Explanation:

Let's consider the following unbalanced equation.

C₆H₁₂O₆ + O₂ = CO₂ + H₂O

We will start balancing H atoms (higher atomicity) by multiplying H₂O by 6.

C₆H₁₂O₆ + O₂ = CO₂ + 6 H₂O

Then, we will balance C atoms by multiplying CO₂ by 6.

C₆H₁₂O₆ + O₂ = 6 CO₂ + 6 H₂O

Finally, to get the balanced equation, we will multiply O₂ by 6.

C₆H₁₂O₆ + 6 O₂ = 6 CO₂ + 6 H₂O

---

Let's consider the following unbalanced equation.

KO₂ + H₂O = KOH + O₂

We will multiply KO₂ and KOH by 2 to balance K and H atoms.

2 KO₂ + H₂O = 2 KOH + O₂

Finally, to get the balanced equation, we will multiply O₂ by 1.5.

2 KO₂ + H₂O = 2 KOH + 1.5 O₂

What is orbit? A. An increase in centripetal motion and mass friction. B. Resistance of an object to avoid friction. C. Gravity causing a curved path as an object tries to go straight. D. How well an object floats.

Answers

Answer:

c

Explanation:

Arrange the following 0.10 M solutions from most acidic to most basic. Justify your rankings.
KOH

KNO3

KCN

NH4Cl

HCl

Answers

KOH is an alkali metal hydroxide and so would be a strong base. HCl is a hydrogen halide in solution, which would be a strong acid (the exception would be HF). There are no other strong bases or acids in this list, so these two substances will comprise our bookends.

KNO3 is a salt produced during the neutralization reaction between KOH and HNO3; the former is (as we just noted) a strong base, and the latter is a strong acid. The salt consisting of the conjugate acid and base of a strong base and acid, respectively, produces a neutral solution in water. So, the KNO3 would be neutral.

KCN in solution consists of the ions K+ and CN-; K+, as we just went through, is the conjugate acid of KOH, a strong base. CN- is the conjugate base of HCN, a weak acid in solution. Since the resultant salt, KCN, is the neutralization product of a strong base and a weak acid, it will be slightly basic in solution (the CN- is a stronger base than K+ is as an acid). So, the KCN solution would be slightly basic.

NH4Cl dissociates in solution to give NH4+ and Cl-. NH4+, as the conjugate acid of the weak base ammonia, NH3, will donate an H+ in water. Cl- is the conjugate base of a strong acid, HCl. The neutralization product of a strong acid (HCl) and a weak base (NH3) would be slightly acidic. So, the solution of NH4Cl would be slightly acidic.

Ranking the solutions from most acidic to most basic (note: it’s important that the solutions have the same concentrations), we get:

HCl (strong acid)
NH4Cl (weak acid salt)
KNO3 (neutral salt)
KCN (weak basic salt)
KOH (strong base).

arrange
these liquids in order of increasing surface tension: water,
hexane, ethanol.

Answers

The magnitude of surface tension of liquid depends on the attractive forces between the molecules. Arrange the following in increasing order of surface tension:

water, alcohol (C2H5OH) and hexane [CH3(CH2)4CH3)].  

Answer:

Hexane, Methanol, Water

Explanation:

I did the assessment

when 70.0 grams of mno2 reacted with 128.0 grams of hcl, the reaction resulted in a 62.7% yield of chlorine gas. what is the actual yield of chlorine gas in grams? Mno2 + HCI —> MnCl2 + h2o + cl2​

Answers

Answer:

35.8g of Cl₂ is the yield

Explanation:

Based on the reaction:

MnO₂ + 4HCl → MnCl₂ + 2H₂O + Cl₂

1 mole of MnO₂ and 4 moles of HCl react producing 1 mole of Cl₂

To solve this question we must find limiting reactant. with limiting reactant we can find the theoretical yield of Cl₂. As the actual yield is the 62.7% we can find actual yield of Cl₂ in grams:

Moles MnO₂ -Molar mass: 86.9368g/mol-:

70.0g * (1mol / 86.9368g) = 0.805 moles

Moles HCl -Molar mass: 36.46g/mol-:

128.0g * (1mol / 36.46g) = 3.51 moles

For a complete reaction of 3.51 moles of HCl are required:

3.51 moles HCl * (1mol MnO₂ / 4mol HCl) = 0.878 moles MnO₂.

As there are just 0.805 moles of MnO₂, MnO₂ is limiting reactant.

1 mole of MnO₂ produce 1 mole of Cl₂. The theoretical moles of Cl₂ produced are 0.805 moles.

As the yield is of 62.7%, the yield of Cl₂ is:

0.805 moles * (62.7 / 100) = 0.505 moles Cl₂. In grams:

0.505 moles Cl₂ * (70.906g / mol) =

35.8g of Cl₂ is the yield

When would a topographic map be useful?

Answers

Answer:

Topographic maps are used by hikers and backpackers to plan routes, estimate travel times, find water, good campsites, and track their progress on hikes. They're designed to depict the three dimensional shape of the world (mountains, valleys, plains, etc.)

Explanation:

1. What do you call the continuous change in position of a body relative to a pon
reference point, as measured by a particular observer in a particular frame
of reference?

Answers

Answer:

In physics, motion means a continuous change in the position of a body relative to a reference point, as measured by a particular observer in a particular frame of reference.

Explanation:

Crosses between true-breeding plants with white flowers produced plants with only _____ flowers white or purple

Answers

The answer is white

The formula for chromium (vi)bromate

Answers

Answer: The formula of chromium fluoride is CFr2.

which sentences in the passage are true?

Answers

Answer:

First and last sentence .‍♀️

Explanation:

An important thing to keep in mind about the Reading Comprehension section of the GRE as we use PowerPrep online to study is that it is just that—reading comprehension. In other words, as difficult as it may seem, and it can be pretty tricky, the test makers will always give us all the information we need in the passage to answer the question.

HELP ASAP PLEASE!!! :)

Answers

Answer:

Alkane

Explanation:

Alkenes have CH in their condensed formulas and alkynes have C in their condensed formulas. There are only CH3 and CH2 so it's an alkane.

A flask contains a 1.00 mole of neon gas and 2.00 moles of argon gas. If the total pressure of the gases is 150.0 kPa, then what is the partial pressure of the argon gas in kPa?

Answers

Answer:

Partial pressure of Ar = 100.5 KPa

Explanation:

The following data were obtained from the question:

Number of mole of Ne = 1 mole

Number of mole of Ar = 2 moles

Total pressure = 150.0 KPa

Partial pressure of Ar =?

Next, we shall determine the mole fraction of Argon (Ar). This can be obtained as follow:

Number of mole of Ne = 1 mole

Number of mole of Ar = 2 moles

Total mole = 1 + 2 = 3 moles

Mole fraction of Ar = mole of Ar / total mole

Mole fraction of Ar = 2/3

Mole fraction of Ar = 0.67 mole

Finally, we shall determine the partial pressure of argon (Ar). This can be obtained as follow:

Mole fraction of Ar = 0.67 mole

Total pressure = 150.0 KPa

Partial pressure of Ar =?

Partial pressure = mole fraction of gas × total pressure

Partial pressure of Ar = 0.67 × 150

Partial pressure of Ar = 100.5 KPa

Estimate your de Broglie wavelength when you are running. (For this problem use h = 10^−34 in SI units and 1 lb is equivalent to 0.45 kg.) For the computation, estimate how fast you can run in meters per second.


A. your running speed ______ m/s

B. your mass ______kg

C. your de Broglie wavelength ______ m

Answers

Answer:

A. your running speed 1.5 m/s

B. your mass 70 kg

C. your de Broglie wavelength [tex]6.32x10^{-36}[/tex]m

Explanation:

Hello there!

In this case, since the equation for the calculation of the Broglie wavelength is:

[tex]\lambda =\frac{h}{m*v}[/tex]

We can assume a running speed of about 1.5 m/s and a mass of 70 kg, so the resulting Broglie wavelength is:

[tex]\lambda =\frac{6.626x10^{-34}kg\frac{m}{s} }{70kg*1.5\frac{m}{s} }\\\\\lambda =6.32x10^-36m[/tex]

Best regards!

What is the mass of a rectangular piece of copper 24.4cm x 11.4 cm x 7.9 cm? The density of copper is 8.92g/cm3.

Answers

The mass of the rectangular piece of copper is 18,869 g (approx).In conclusion, the mass of a rectangular piece of copper with dimensions 24.4cm x 11.4 cm x 7.9 cm and a density of 8.92 g/cm³ is 18,869 g (approx.).

The given dimensions of the rectangular piece of copper are:Length = 24.4 cmWidth = 11.4 cmHeight = 7.9 cmThe formula to calculate the mass of an object is given by;

Mass = Density x Volume

Here, the density of copper is given as 8.92 g/cm³.

Therefore, the first step is to calculate the volume of the rectangular piece of copper.The formula to calculate the volume of a rectangular object is given by:

Volume = Length x Width x Height

So,Volume = 24.4 cm x 11.4 cm x 7.9 cm= 2115.432 cm³Now we will use the mass formula:

Mass = Density x Volume= 8.92 g/cm³ x 2115.432 cm³= 18,869.27824 g= 18,869 g (approx.)

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Which of the following is NOT an abiotic factor that influences an ecosystem?

Amount of water available

Average rainfall

Average temperature

Number of different animals

Answers

Answer:

Number of different animals

Explanation:

Number of different animals is not an abiotic factor that influences an ecosystem rather it is  a biotic factor.

What is an ecosystem?

Ecosystem is defined as a system which consists of all living organisms and the physical components with which the living beings interact. The abiotic and biotic components are linked to each other through nutrient cycles and flow of energy.

Energy enters the system through the process of photosynthesis .Animals play an important role in transfer of energy as they feed on each other.As a result of this transfer of matter and energy takes place through the system .Living organisms also influence the quantity of biomass present.By decomposition of dead plants and animals by microbes nutrients are released back in to the soil.

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How do you balance this:
Br2 + H2O + SO2 = HBr + H2SO4

Answers

Answer:

Br2+ 2H2O + SO2= 2HBr + H2SO4

Let's Compare the left side of the equation to the right side of the equation.

Left: Br= 2, H= 2, S= 1, O = 1+2

Right: Br=1, H= 1+2, S=1, O= 4

We can see that only S is balanced and not the other 3 elements.

I'll try to make each element balance.

For Br; I'll multiply by 2 on the left to make it equal to the right.

For H; Since the 2 for Br on the right affected also H, that H ( for HBr) Already has a 2, but then it adds with the other H2( for H2SO4) to give a total of 4 H on the right side. But then there's only 2 H on the left. so we multiply that 2 by a 2 ( which is written infront of the H2O to give a total of 4 H on the left side.

For O; Because of the 2 infront of the H2O, it affects the O in H2O..so now we have 2 O plus the 2 O ( in SO2) to give a total of 4 O which is equal to the right side.

Question 9 of 10
Which of the following statements are true of nuclear energy and reactors?
Check all that apply.
O A. Nuclear reactors on Earth use fusion reactions to produce energy.
B. Nuclear fission reactions use only a small amount of material to
produce a large amount of energy.
C. Nuclear reactors use controlled reactions.
D. Nuclear fission is done by joining nuclei together into a bigger
nucleus.

Answers

Answer:

B. Nuclear fission reactions use only a small amount of material to

produce a large amount of energy.

C. Nuclear reactors use controlled reactions.

Explanation:

Nuclear reactors are devices that contain and control nuclear chain reactions while releasing heat produced from these nuclear chain reactions at a controlled rate.

A nuclear power plant uses the enormous amount of heat that are produced from the nuclear chain reactions occurring in the nuclear reactor to turn water into steam, which then drives turbine generators that generate electricity.

The nuclear chain reactions occurring in the nuclear reactor are fission chain reactions. A nuclear fission reaction is a reaction in which a larger atom is split into two or more smaller atoms when bombarded with energetic neutrons resulting in the release of large amounts of energy and more neutrons. The neutrons released split more atoms of the larger atom into smaller atoms in what is known as a chain reaction. This reaction is controlled by means of moderators. A moderator helps slow down the neutrons produced by fission to sustain the chain reaction.

Statements that are right as regards nuclear energy and reactors are ;

B. Nuclear fission reactions use only a small amount of material to

produce a large amount of energy.

C. Nuclear reactors use controlled reactions.

Nuclear fission can be regarded as splitting of a large atomic nucleus into smaller nuclei, in this case neutron is absorbed into a nucleus. It utilize small material to produce energy.

This process is done by the use of nuclear reactor which brings about a  controlled reaction.

Therefore option B,C, are correct.

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Which oficial the following organisms si not an autotroph

A. mushroom
B. grass
C. tree
D. moss​

Answers

Answer:

A. mushroom

Explanation:

Maybe option A because mushrooms ain't makes their food.

Why is water called a universal solvent?
A. It is less soluble in warmer temperatures.
B. It is able to dissolve almost any solute.
C. It is only able to dissolve a small amount of sugar.
D. It is less soluble in colder temperatures.

Answers

Answer: B

Explanation:

Water is called the "universal solvent" because it dissolves more substances than any other liquid.

B mark me brainliest please

4
The work done when a gas is compressed in a cylinder is 338 J. At the same time,
it absorbs 142 J of heat from the surroundings. Compute the change in energy of
the system.

Answers

Answer:

bbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbbb

Explanation:

kh uh

Can someone help me with this 3 questions I’ll mark brainliest spam answers will be reported

Answers

1. A
2. A
3. C
Your welcome

Answer:

1. stomach

2. veins

3.both are functions

Explanation:

1. The cardiovascular system consists of the heart, and a closed system of vessels called arteries, veins, and capillaries. (Stomach is not included)

2.The inferior vena cava is the largest vein in the body and carries deoxygenated blood from the lower half of the body into the heart

3. Blood transports oxygen and nutrients to the lungs and tissues, and  brings waste products to the kidneys and liver, which filter and clean the blood.

Hope this helps!

What is orbit? A. An increase in centripetal motion and mass friction. B. Resistance of an object to avoid friction. C. Gravity causing a curved path as an object tries to go straight. D. How well an object floats.

Answers

Answer:

C. gravity causing a curved path as an object tries to go straight.

Other Questions
(-4 5/8) - (-1 1/4) = What is the slope of the line that passes through the points (3, 2) and (1,2)? Write your answer in the simplest form I dont know what to put as the answer for this question Fechner's law in experimental psychology was first hypothesized in the 1860s. It describes the relationship between a change in sensory stimulus and the perceived change in the stimulus. Examples include adding one tsp of sugar to a cup of tea (stimulus change) and sensing how much sweeter the tea tastes (perception change) increasing the weight of an object you're holding (stimulus change) and sensing how much heavier the object feels (perception change) Let's look at this second situation. Let s be the weight of an object in grams, and let P(s) be the perceived weight of the object to someone holding it. Fechner's law says for some constant k > 0, k dP ds (a) Translate the differential equation to a sentence by filling in the blanks: The rate of change of with respect to a change in to the is Words you might use are time, weight, perceived weight, proportional, inversely proportional, equal. (b) Check that P(s) = k ln(s) + C is a solution to Fechner's law for any constant C. (c) Suppose that 0.5 grams is the threshhold stimulus, the highest actual weight at which a person cannot perceive any weight. In other words, holding 0.5 grams feels like holding zero weight. Find the particular solution to Fechner's law given this initial value. (d) What does your solution from part (b) predict for the perceived weight of an object of weight 0.25 grams should be? Does this make sense? If so, explain why, and if not, suggest a way to improve the model. 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Suspension bridgesOD. Stone head sculptures The expected return for the general market is 15%, and the risk premium is 10%. The beta of Ncell is 1.25. What is the required rate of return for Ncell? O 23.75% O 11.25% O 12.50% O 17.50% If Country R has less income inequality than Country T, which of the following must be true?Country R will have greater wealth overall.Country T will have greater wealth overall. Country R will have more people in poverty than Country T.Country R will have a higher Gini coefficient than Country T.Country R will have a lower Gini coefficient than Country T. *Use the high-low method*Mason Company uses the high-low method to predict its totaloverhead costs. Past records show that total overhead cost was$25,000 for 800 labour hours worked and $27,500 for A primary runway is being designed for a new airport to serve airport approach category B. As part of this work it is required to design two consecutive vertical curves (a crest vertical curve followed by a sag vertical curve) to be located midway along the length of the runway. The design should satisfy all the grade and minimum length requirements. If conditions are such that the crest vertical curve connects grades of +0.5% and + 1.5%, determine all the properties of both curves that will be necessary to set out the curves. The elevation and station of the point of intersection of the two tangents of the crest vertical curve are 556.50 ft and 595 + 45.00, respectively, and the distance between the points of intersections (PVIs) of the vertical curves is 975 ft. Who were they? Thurgood MarshallMalcom XRose parks Use the triangle shown to answer the questions that follow.15 mX32a) Using the 32 as the reference angle, label the hypotenuse (h), adjacent (a) and opposite (0).b) Which trig function (cos, sin, or tan) could be used to solve for x?c) Solve for x.